Synthesis of l-(+)-Tartaric Acid from l-Ascorbic Acid via 5-Keto-d-Gluconic Acid in Grapes
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Synthesis of l-(+)-Tartaric Acid from l-Ascorbic Acid via 5-Keto-d-Gluconic Acid in Grapes.
5-Keto-l-idionic acid ( identical with5-keto-d-gluconic acid, d-xylo-5-hexulosonic acid) was found as a metabolic product of l-ascorbic acid in slices of immature grapes, Vitis labrusca L. cv ;Delaware'. Specifically labeled compounds, recognized as metabolic products of l-ascorbic acid in grapes, were fed to young grape tissues to investigate the metabolic pathway from l-ascorbic acid to l-(+)...
متن کاملBiological synthesis of L-ascorbic acid in animal tissues: conversion of D-glucuronolactone and L-gulonolactone into L-ascorbic acid.
Simpson, S. A. & Tait, J. F. (1952). Endocrinology, 50, 150. Simpson, S. A. & Tait, J. F. (1953). Mem. Soc. Endocrin. 2,9. Southcott, C. M., Bandy, H. E., Newsom, S. E. & Darrach, M. (1956). Canad. J. Biochem. Phy8iol. 34, 913. Speirs, R. S. & Meyer, R. K. (1951). Endocrinology, 48, 316. Vogt, M. (1955). J. Physiol. 130, 601. Vogt, M. (1957). Ciba Foundation Colloq. Endocrin. 11, 193. Weichselb...
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The biosynthetic pathway of L-tartaric acid, the form most commonly encountered in nature, and its catabolic ties to vitamin C, remain a challenge to plant scientists. Vitamin C and L-tartaric acid are plant-derived metabolites with intrinsic human value. In contrast to most fruits during development, grapes accumulate L-tartaric acid, which remains within the berry throughout ripening. Berry t...
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In the title compound, C(4)H(8)N(2)O(3)·C(4)H(6)O(6), the amino acid mol-ecule exists as a zwitterion and the carb-oxy-lic acid in an un-ionized state. The tartaric acid mol-ecules are linked into layers parallel to the ab plane by O-H⋯O hydrogen bonds. The amino acid mol-ecules are also linked into layers parallel to the ab plane by N-H⋯O and C-H⋯O hydrogen bonds. The alternating tartaric acid...
متن کاملThe synthesis of L-ascorbic acid in the rat from D-glucuronolactone and L-gulonolactone.
Previous studies have shown that the intact carbon chain of glucose is utilized for the synthesis of L-ascorbic acid in the rat (l-3). Evidence for this precursor relationship came from experiments in which the administration of carbon land carbon 6-labeled glucose tracers resulted in the urinary excretion of n-ascorbic acid labeled predominantly in carbon 6 and carbon 1, respectively. Although...
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ژورنال
عنوان ژورنال: Plant Physiology
سال: 1984
ISSN: 0032-0889,1532-2548
DOI: 10.1104/pp.76.1.170